Regio- and stereoselectivity of polar [2+3] cycloaddition reactions between (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone and selected (E)-2-substituted nitroethenes

dc.contributor.author	Demchuk, Oleg M.
dc.contributor.author	Jasiński, Radomir
dc.contributor.author	Ziółkowska, Magda
dc.contributor.author	Maziarka, Agata
dc.date.accessioned	2022-06-24T09:37:19Z
dc.date.available	2022-06-24T09:37:19Z
dc.date.issued	2014
dc.description.abstract	[2+3] Cycloaddition reactions of the highly reactive (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone with (E)-2-R-nitroethenes proceed under mild conditions and yield mixtures of stereoisomeric 2-methyl-3-(3,4,5-trimethoxyphenyl)-4-nitro-5-R-isoxazolidines. The effect of regiospecificity of the cycloadditions may be accounted for by the theory of electrophilicity indexes. Stereoselectivity, however, is determined by a compilation of steric and secondary orbital effects.	pl
dc.identifier.citation	"Central European Journal of Chemistry", 2014, Vol. 12, nr 5, s. 586-593	pl
dc.identifier.doi	10.2478/s11532-014-0518-2
dc.identifier.uri	http://hdl.handle.net/20.500.12153/3239
dc.language.iso	en	pl
dc.publisher	Versita	pl
dc.rights	Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/pl/	*
dc.subject	[2+3] cycloaddition	pl
dc.subject	Nitrone	pl
dc.subject	Nitroalkene	pl
dc.subject	Regioselectivity	pl
dc.subject	Stereoselectivity	pl
dc.title	Regio- and stereoselectivity of polar [2+3] cycloaddition reactions between (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone and selected (E)-2-substituted nitroethenes	pl
dc.type	info:eu-repo/semantics/article	pl

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