A clean and simple method for deprotection of phosphines from borane complexes

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dc.contributor.authorDemchuk, Oleg M.
dc.contributor.authorJasiƄski, Radomir
dc.contributor.authorStrzelecka, Dorota
dc.contributor.authorDziuba, Kamil
dc.contributor.authorKula, Karolina
dc.contributor.authorChrzanowski, Jacek
dc.contributor.authorKrasowska, Dorota
dc.date.accessioned2022-06-23T13:05:36Z
dc.date.available2022-06-23T13:05:36Z
dc.date.issued2017
dc.description.abstractSimple, efficient, clean, and stereospecific protocols of protection of phosphorus atom with borane and deprotection from the borane complexes of the tertiary phosphines in mild conditions are reported. The proposed protection/deprotection reactions tolerate a range of functional groups and lead to pure products with excellent yield with no need for application of chromatographic or crystallisation purification procedures. For the first time mechanisms of the reactions of phosphine protection and deprotection have been studied based on experimental kinetic data as well as quantumchemical calculations, which allows designing reaction conditions suitable for a given substrate.pl
dc.identifier.citation"Pure and Applied Chemistry", 2017, Vol. 90, nr 1, s. 49-62pl
dc.identifier.doi10.1515/pac-2017-0313
dc.identifier.urihttp://hdl.handle.net/20.500.12153/3236
dc.language.isoenpl
dc.publisherWalter de Gruyterpl
dc.subjectchiral phosphinespl
dc.subjectICGC-6pl
dc.subjectphosphine boranespl
dc.subjectprotection and deprotection reactionspl
dc.subjectquantumchemical DFT calculationspl
dc.subjectreaction mechanism elucidationpl
dc.titleA clean and simple method for deprotection of phosphines from borane complexespl
dc.typeinfo:eu-repo/semantics/articlepl
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