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Title: Green in water sonochemical synthesis of tetrazolopyrimidine derivatives by a novel core-shell magnetic nanostructure catalyst
Authors: Demchuk, Oleg M.
Maleki, Ali
Rahimi, Jamal
Wilczewska, Agnieszka Z.
Jasiński, Radomir
Keywords: Core shell nanocatalyst; Green chemistry; Magnetic nanoparticles; Tetrazolopyrimidine; Ultrasonic irradiation
Issue Date: 2018
Publisher: Elsevier
Citation: "Ultrasonics Sonochemistry", 2018, Vol. 43, s. 262-271
Abstract: A green approach for the one-pot four-component sonochemical synthesis of 5-methyl-7-aryl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylic esters from the reaction of 2-cyano-guanidine, sodium azide, various aromatic aldehydes and methyl or ethyl acetoacetate in the presence of a catalytic amount of Fe2O3@SiO2-(CH2)3NHC(O)(CH2)2PPh2 as a new hybrid organic–inorganic core–shell nanomagnetic catalyst is described. This is the first design, preparation, characterization and application of the present nanomaterial and also the first ultrasound irradiated synthesis of the biologically and pharmaceutically important heterocyclic compounds in water as a green solvent. This novel sonocatalysis/nanocatalysis protocol offers several advantages such as high yields, short reaction times, environmentally-friendly reaction media, easily isolation of the products, simple preparation, full characterization and recoverability of the nanocatalyst by an external magnet and reusing several times without significant loss of activity.
DOI: 10.1016/j.ultsonch.2017.12.047
ISSN: 1350-4177
Appears in Collections:Artykuły naukowe (WNŚiNoZ)

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